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Synthesis of amphiphilic copolymers based on acrylic acid, fluoroalkyl acrylates and n -butyl acrylate in organic, aqueous–organic, and aqueous media via raft polymerization †.
* Corresponding authors
a Moscow Technological University, Institute of Fine Chemical Technologies, Vernadskogo pr., 86, Moscow, Russian Federation
b Max-Planck Institute of Colloids and Interfaces, Am Mühlenberg 1, 14476 Potsdam, Germany
c Faculty of Chemistry, Lomonosov Moscow State University, Lenin Hills, 1, bld.3, Moscow, Russian Federation E-mail: [email protected]
d Faculty of Physics, Lomonosov Moscow State University, Lenin Hills, 1, bld.2, Moscow, Russian Federation
e Institute of Advanced Energy Related Nanomaterials, University of Ulm, Albert Einstein Allee, 11, Ulm, Germany
Amphiphilic narrow dispersed copolymers of acrylic acid and fluoroalkyl acrylates are synthesized via reversible addition–fragmentation chain transfer (RAFT) polymerization using dibenzyl trithiocarbonate in DMF solution. These copolymers and polyacrylic acid containing the trithiocarbonate group within the polymeric chain are used for the synthesis of triblock copolymers in organic, aqueous–organic or aqueous media by chain extension with n -butyl acrylate or its mixture with fluoroalkyl acrylates. Both dispersion polymerization and emulsifier-free emulsion polymerization lead to self-assembling of triblock copolymers in the core–shell particles; the former route provides the formation of microstructured polymer films with a percolated structure.
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N. S. Serkhacheva, O. I. Smirnov, A. V. Tolkachev, N. I. Prokopov, A. V. Plutalova, E. V. Chernikova, E. Yu. Kozhunova and A. R. Khokhlov, RSC Adv. , 2017, 7 , 24522 DOI: 10.1039/C7RA03203J
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Amphiphilic narrow dispersed copolymers of acrylic acid and fluoroalkyl acrylates are synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization using dibenzyl trithiocarbonate in DMF solution. These copolymers and polyacrylic acid containing the trithiocarbonate group within the polymeric chain are used for the synthesis of triblock copolymers in organic, aqueous ...
The data on successful application of isothermal amplification methods for the analysis of cells and biomolecules with the use of DNA/RNA aptamers are presented. DOI: 10.1134/S0006297920020030. Keywords: nucleic acids, amplification, isothermal, bioanalysis, aptamers. Quantitative and qualitative determination of nucle ic acids is an important ...